Angelina Jolie and Brad Pitt
Cover Images/Dara Kushner
Celebrity

While some of these couples manage to prove that their love is one that can survive the hardships, some other marriages ended as ugly as how they began.

AceShowbiz - Angelina Jolie and Brad Pitt was another of famous Hollywood couples who found love on the set of their movie. The pair sparked rumors of romantic relationship after they worked on "Mr and Mrs Smith" (2005), while he was still married to Jennifer Aniston, another of Hollywood's "It Girls." Angelina admitted she and Brad fell in love during the filming of their movie, but vehemently dismissed allegations of affair.

After Brad and Jennifer announced their separation in 2005, Angelina confirmed she was expecting her first child together with the "Moneyball" star less than a year later. They went on to have six children together. However, after 12 years together and 2 years of marriage, they separated in 2016 and have been entangled in a long custody battle over their minor children.

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